Abstract: The values of knowledge talents have high sensitive. Core Values identity and psychological well-being has affection to successful intelligence. Based on the sample data of knowledge talent and by means of structural equation modeling, empirical studies have revealed the intrinsic relationship among core values identity, psychological well-being and success intelligence, and discovered the existence of microscopic mechanism and path of excitation, and provides a new mode of thinking for the development of successful intelligence of knowledge workers. The research founds:core values identity promotes the psychological well-being; core values identity promotes the growth of analytical intelligence, creative intelligence and practice-based intellectual; subjective well-being promotes the growth of the analytical intelligence, creative intelligence and practical intelligence.

Key words: Core Values identity, psychological well-being, successful intelligence, knowledge workers